Functionalization Of Carborane Via Carboryne Intermediates (springer Theses)
by Da Zhao /
2016 / English / PDF
7.8 MB Download
This thesis focuses on the development of new methods of
functionalizing carboranes using
This thesis focuses on the development of new methods of
functionalizing carboranes usingo
o-carboryne
intermediates. Functional carboranes are now finding a broad
range of applications, including organic synthesis, drug design,
polymers, catalysis, metal-organic frameworks, electronic devices
and more. However, the limited number of efficient synthetic
methods for obtaining functional carborane materials has
restricted their applications. The methodologies established in
this thesis represent simple, yet powerful strategies to assemble
previously inaccessible, useful complex molecules, which will
also have a significant impact on future synthetic, cluster and
materials chemistry. Moreover, it discusses the first method for
the in situ generation of electrophilic boron radical using
photocatalysis.
-carboryne
intermediates. Functional carboranes are now finding a broad
range of applications, including organic synthesis, drug design,
polymers, catalysis, metal-organic frameworks, electronic devices
and more. However, the limited number of efficient synthetic
methods for obtaining functional carborane materials has
restricted their applications. The methodologies established in
this thesis represent simple, yet powerful strategies to assemble
previously inaccessible, useful complex molecules, which will
also have a significant impact on future synthetic, cluster and
materials chemistry. Moreover, it discusses the first method for
the in situ generation of electrophilic boron radical using
photocatalysis.
